MEE 6501 Advanced Air Quality U81 - Science
minimum 500 words APAuse references and in text citations. Discuss the engineering options available, the mode of action for capturing particle-phase pollutants from air, and the advantages and disadvantages of each as an option in air quality system designs.
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UNIT VIII STUDY GUIDE
Utilizing Pollution Control
Technologies for Engineered Air
Quality Control
Course Learning Outcomes for Unit VIII
Upon completion of this unit, students should be able to:
7. Evaluate air pollution control technologies.
7.1 Discuss air pollution control technologies for particulate-phase pollutants.
7.2 Discuss air pollution control technologies for gas-phase pollutants.
Course/Unit
Learning Outcomes
7.1
7.2
Learning Activity
Unit Lesson
Chapter 9, pp. 331-352
Chapter 10, pp. 355-385
Unit VIII Assessment
Unit Lesson
Chapter 9, pp. 331-352
Chapter 10, pp. 355-385
Unit VIII Assessment
Reading Assignment
Chapter 9: Control of Motor Vehicle Emissions, pp. 331–352
Chapter 10: Control of Emissions from Stationary Sources, pp. 355–385
Unit Lesson
Independent Variables
To date, we have discussed a tremendous amount of chemistry, particle science, atmospheric science, and
statistical analysis. We have worked within these different disciplines using mathematics as the common
language in order to effectively approach air quality from a general systems, theory-based engineering
perspective. We can most likely agree that engineering air quality has demonstrated to be an interdisciplinary
science of its own!
In this unit, we want to comprehensively consider all of the work that we have done to understand the
independent variables causally related to air quality. If we take this critical view now, we have a much better
opportunity to carefully select the appropriate engineering control for the independent variables of concern in
our air. Consequently, we must first understand that our air quality control options are going to largely fall into
one of two categories: particulate-phased pollutants or gas-phased pollutants. Understanding each will inform
us to make the best possible decision when engineering the air quality controls for our systems.
According to Godish, Davis, and Fu (2014), particulate-phased pollutants (measured as a percentage of
particulate matter or PM) really have about three main capture strategies that are effective for improving air
quality. These include cyclonic collection, electrostatic collection, and numerous methods of filtration
collection.
Controls
Settling chambers, impingers, and cyclones are designed to capture large to medium-sized particles of all
types of pollutants. These may include elutriators for aerosol particle collection as well as cyclones (to include
MEE 6501, Advanced Air Quality Control
1
aerosol centrifuges). The documented benefits include their relatively lower costs,
operation,
UNITsimplicity
x STUDYofGUIDE
durability, and generally low maintenance. However, disadvantages include relatively
Title low efficiencies for
smaller particles, the propensity for erosion of components due to abrasive actions of particles, and the large
space required to accommodate the equipment (Phalen & Phalen, 2013; Godish et al., 2014).
Electrostatic precipitators (including mist precipitators) are designed to operate at high temperatures while
creating a moisture-laden air as the capture medium. This makes electrostatic capture very efficient for very
fine particles. The advantages include the compact nature of the equipment, the lack of dust generation
during the capture process, and the constant pressure drop to the system during particle capture. Still, among
the most significant disadvantages of the design are the large space requirements for the equipment, the
relatively higher initial costs, and the phenomena of some pollutant particle charges not being matched well
enough to the system for efficient capture (Phalen & Phalen, 2013; Godish et al., 2014).
Filtration options include traditional filtration systems (such as medium filters) that are excellent for capturing
dust, fumes, and non-sticky particles with a wide disparity of sizes. This makes for highly efficient systems,
moderate power requirements, and a nice, dry, disposable waste. However, the low initial cost is often off-set
with higher bag replacement costs (such as replacing entire bag houses during maintenance shut-downs),
and the potential for fire hazards seem to be intrinsically higher in these designs (Phalen & Phalen, 2013;
Godish et al., 2014).
More advanced filtration options include spray chambers and wet scrubbers (to include venturi scrubbers and
wet cyclones). These afford very small particle captures, constant pressure drops (not unlike electrostatic
precipitators), and no dust generation. Still, one of the disadvantages of the design is that the process
involves water. As such, the waste water generated from the process creates another waste stream that must
be handled properly for pre-treatment and ultimate disposal (Phalen & Phalen, 2013; Godish et al., 2014).
According to Godish et al. (2014), gas-phased pollutant capture strategies include a few more options than
PM capturing. These include thermal oxidizing (thermal oxidizers, flaring, and catalytic systems), adsorption
(packed sorbent beds), absorption (scrubbing), and biological treatment. The different options available within
each of these strategies afford the engineer to aptly match the diverse types of gas pollutants to the control.
Thermal oxidizers or “afterburners” are gas combustion chambers with temperatures typically ranging from
540ºC to 815ºC. These systems are robust enough to accommodate a moderate range of gases and work
similarly to a flare in terms of simply combusting the gas mixtures into less complex gases. There are
normally very few maintenance requirements for this technology, and the process is very efficient. However,
as with any combustion-related process, carbon dioxide (CO2) and carbon monoxide (CO) are still potential
outcomes as byproducts of combustion (Phalen & Phalen, 2013; Godish et al., 2014).
Flare systems are typically used specifically for hydrocarbon-rich gases within a range of concentration just
below the upper explosive limit (UEL) and just above the lower explosive limit (LEL). The benefit is that the
explosive gases are combusted, often close to or exceeding 99\% efficiency. The disadvantage is that, not
unlike afterburners, natural gas is often used as a prime for the flare system to keep the pilot lit, even while
producing other byproducts of combustion (Phalen & Phalen, 2013; Godish et al., 2014).
Catalytic systems (catalytic oxidizers or catalytic converters) are actually catalyst-filled filters that typically
operate at elevated temperatures between 370ºC to 480 ºC to treat gases at or near the LEL (Phalen &
Phalen, 2013). Benefits include the low maintenance requirements associated with thermal oxidation as well
as the low system-pressure drop that is also indicative of electrostatic precipitators. However, one of the most
routinely leveraged benefits is the use of this technology to reduce the footprint (size) and fuel use of other
systems. Disadvantages include the inefficiencies inherent in the design during colder temperatures, the
strong potential for particles to clog the catalytic converter, and the seemingly growing expense of catalyst
replacement (Phalen & Phalen, 2013; Godish et al., 2014).
MEE 6501, Advanced Air Quality Control
2
UNIT x STUDY GUIDE
Title
This is a close-up view of cross section of honeycomb interior structure of a catalytic system. The precious
elements used in these systems, such as platinum and palladium, cause a cost-disadvantage for these
systems.
(Baloncici, 2011)
Adsorption systems (packed beds) are designed to leverage the adherence (sticking nature) of gas molecules
through the van der Waals attractional force phenomena. These can be through either solid or liquid
adsorption systems. As discussed at length by Godish et al (2014), this is often accomplished with solid
media systems by packing beds with various packing media of metal, glass, plastic beads, and activated
charcoal in order to create a sorbent environment for the molecules traveling through the system. The polarity
of the molecules helps to inform the engineer of the appropriate media to use in the system, targeting the gas
molecules of interest for capture. This specificity of gas molecule targeting is among the benefits of this type
of technology, as well as the relative ease of incorporating higher temperature gases for destruction of
specific gases (such as heating potassium permanganate for destruction). However, disadvantages include
the fact that since there is a pressurized gas stream, clogging of the system is possible as well as the
potential that flammable media—like activated charcoal—could become compounded with the adsorption of
other flammable organics (Phalen & Phalen, 2013; Godish et al., 2014). Liquid media systems may also be
used, given the benefit of collecting the fluid media for recycle and reuse. However, disadvantages of the
liquid media system are the increased costs associated with many of the liquids effective at capturing the
select gas molecules, corrosion problems, and the strong potential for accidental contamination of the system
(Phalen & Phalen, 2013).
Absorption systems (gas adsorption through liquid) or scrubbers are discussed by Godish et al. (2014) as
also having the options of either solid or liquid-phased media designs. For example, solid-phased media
scrubbers include packed tower scrubber designs that can accommodate select gas molecule captures
through sodium carbonate, lime, or other pack media. Additionally, flue gas and other similar gases may be
dry scrubbed with aerosol or aerosol slurries injected as an atomized mist, then subsequently semi-dried in a
reaction chamber. Liquid-phase media scrubbers include water mixed with select mineral slurries or even
acids. For example, a common industry practice for cleaning an ammonia nitrogen (NH 3) gas stream is by
scrubbing with a wet scrubber that mists water and sulfuric acid (H2SO4), in order to reduce the ammonia to
the ammonium salt of ammonium sulfate ((NH4)2SO4). Interestingly, both the benefits and disadvantages of
these system designs are similar to adsorption systems (Phalen & Phalen, 2013; Godish et al., 2014).
Biological treatment system options are appropriate when attempting to digest (rather than capture) gases
such as organic acids, ketones, esters, and other toxic gases. These bioscrubbers are discussed by Godish
et al. (2014) with several different design types. The advantages of these systems include their relative
efficiency. Still, disadvantages include the higher maintenance requirements, the cost of the microbes
MEE 6501, Advanced Air Quality Control
3
necessary to keep the biofilters and packing beds charged, and the temperature
andx pressure
sensitivity
UNIT
STUDY GUIDE
differences among microbes (Phalen & Phalen, 2013; Godish et al., 2014). Title
This discussion completes our in-depth study of air quality engineering, and it prepares us as graduate-level
engineers to specify the appropriate control technology for applications not unlike the industrial coating (paint)
spray booth in our course project scenario. We now understand that we have options for capturing both solid
aerosol particles and organic gas molecules within our work system prior to discharging the air through the
ventilation system and out into the ambient air environment. Your work over these eight units has prepared
you to understand the steps required to actively engineer air quality rather than to passively monitor and
manage it.
You can be proud of your demonstrated applied learning in this course. This course has effectively challenged
you to pull from your growing knowledge of chemistry, physics, and atmospheric science, gained throughout
this entire graduate-level program. You are ready. Let’s go engineer some air quality into our environment!
References
Baloncici. (2011). Catalytic converter, (ID 29963108) [Photograph]. Retrieved from
https://www.dreamstime.com/royalty-free-stock-photos-catalytic-converter-honeycomb-interiorstructure-emissions-control-image29963108
Godish, T., Davis, W. T., & Fu, J. S. (2014). Air quality (5th ed.). Boca Raton, FL: CRC Press.
Phalen, R. F., & Phalen, R. N. (2013). Introduction to air pollution science: A public health perspective.
Burlington, MA: Jones & Bartlett Learning.
MEE 6501, Advanced Air Quality Control
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